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[城市固体废弃物焚烧飞灰的基本特性]

[Fundamental properties of fly ash from municipal solid waste incineration].

作者信息

Wang Jun, Jiang Jian-Guo, Sui Ji-Chao, Yang Shi-Jian, Zhang Yan

机构信息

Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.

出版信息

Huan Jing Ke Xue. 2006 Nov;27(11):2283-7.

Abstract

Fundamental properties and the factors that influence the distribution of heavy metals of several fly ashes are analyzed. Experiments indicate that the structures are complex and the properties are changeable. The study results show that the chemical composition is Cl, Ca, K, Na, Si, Al, O, etc, and heavy metals are Zn, Pb, Cr, Cu etc. The main structures of fly ash are irregularly amorphous forms and polycrystalline aggregates. Generally, the ieaching toxicity exceeds the identification standard for hazardous wastes. Heavy metals are chiefly in the forms of tiny aerosol particles and aggregates on the surface of fly ash. The properties of fly ash are greatly influenced by the change of incinerators or the variation of incinerating time. The content of Cl ranges from 6.93% to 29.18%, while that of SiO2 does from 4.48% to 24.84%. The leaching toxicity varies between 0 and 163.10 mg x L(-1) (Pb) and between 0.049 and 164.90 mg x L(-1) (Zn).

摘要

分析了几种粉煤灰的基本性质以及影响重金属分布的因素。实验表明,其结构复杂且性质多变。研究结果表明,化学成分有氯、钙、钾、钠、硅、铝、氧等,重金属有锌、铅、铬、铜等。粉煤灰的主要结构为不规则无定形形态和多晶聚集体。一般来说,浸出毒性超过危险废物鉴别标准。重金属主要以微小气溶胶颗粒和粉煤灰表面聚集体的形式存在。粉煤灰的性质受焚烧炉变化或焚烧时间变化的影响很大。氯含量在6.93%至29.18%之间,而二氧化硅含量在4.48%至24.84%之间。浸出毒性在0至163.10毫克/升(铅)之间以及在0.049至164.90毫克/升(锌)之间变化。

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