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[城市固体废弃物焚烧飞灰中重金属的螯合稳定化用于卫生填埋共处置]

[Chelating stabilization of heavy metals in fly ash from municipal solid waste incinerators for co-disposal in sanitary landfill].

作者信息

Ye Tun-min, Wang Wei, Gao Xing-bao, Wan Xiao

机构信息

Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.

出版信息

Huan Jing Ke Xue. 2008 Apr;29(4):1119-23.

Abstract

The characteristics and leaching behavior of heavy metals in fly ash, sampled from 4 MSWI plants, were investigated in this study. The results indicated that the main elements of fly ash were Si, Ca, Al, Cl, and heavy metals such as lead, zinc, copper, chromium and cadmium were enriched in fly ash which had great environmental risk. However, co-disposal of fly ash in sanitary landfill was an available and practical resolvent. For disposal security, the leaching procedure of toxicity basing on co-disposal scenario, which had been implemented from 1st May 2007, had increased the acidity of leachant to 0.3 mol x L(-1). The experiments of chelating stabilization technology using dithiocarbamate were carried out for MSWI fly ash treatment. The results indicated that heavy metals in fly ash were fixed by DTC in manner of chelating reaction. With the amount of additive reaching 3% (mass fraction), the concentrations of heavy metals in leachate of these fly ash samples could meet the demand of co-disposal in sanitary landfill.

摘要

本研究对取自4座城市生活垃圾焚烧厂的飞灰中重金属的特性及浸出行为进行了调查。结果表明,飞灰的主要元素为硅、钙、铝、氯,铅、锌、铜、铬和镉等重金属在飞灰中富集,具有较大的环境风险。然而,将飞灰共处置于卫生填埋场是一种可行且实际的解决方法。为了处置安全,自2007年5月1日起实施的基于共处置方案的毒性浸出程序已将浸出液的酸度提高到0.3 mol·L(-1)。开展了使用二硫代氨基甲酸盐的螯合稳定化技术处理城市生活垃圾焚烧飞灰的实验。结果表明,飞灰中的重金属通过二硫代氨基甲酸盐以螯合反应的方式被固定。当添加剂用量达到3%(质量分数)时,这些飞灰样品浸出液中重金属的浓度可满足卫生填埋共处置的要求。

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