Werther Joachim
Hamburg University of Technology, Institute of Solids Process Engineering and Particle Technology, D 21071 Hamburg, Germany.
J Hazard Mater. 2007 Jun 18;144(3):604-13. doi: 10.1016/j.jhazmat.2007.01.116. Epub 2007 Jan 31.
An overview is given on methods and technologies for limiting the gaseous emissions from waste combustion. With the guideline 2000/76/EC recent European legislation has set stringent limits not only for the mono-combustion of waste in specialized incineration plants but also for co-combustion in coal-fired power plants. With increased awareness of environmental issues and stepwise decrease of emission limits and inclusion of more and more substances into the network of regulations a multitude of emission abatement methods and technologies have been developed over the last decades. The result is the state-of-the-art waste incinerator with a number of specialized process steps for the individual components in the flue gas. The present work highlights some new developments which can be summarized under the common goal of reducing the costs of flue gas treatment by applying systems which combine the treatment of several noxious substances in one reactor or by taking new, simpler routes instead of the previously used complicated ones or - in the case of flue gas desulphurisation - by reducing the amount of limestone consumption. Cost reduction is also the driving force for new processes of conditioning of nonhomogenous waste before combustion. Pyrolysis or gasification is used for chemical conditioning whereas physical conditioning means comminution, classification and sorting processes. Conditioning yields a fuel which can be used in power plants either as a co-fuel or a mono-fuel and which will burn there under much better controlled conditions and therefore with less emissions than the nonhomogeneous waste in a conventional waste incinerator. Also for cost reasons, co-combustion of wastes in coal-fired power stations is strongly pressing into the market. Recent investigations reveal that the co-firing of waste can also have beneficial effects on the operating behavior of the boiler and on the gaseous emissions.
本文概述了限制垃圾焚烧过程中气体排放的方法和技术。根据2000/76/EC号指令,近期欧洲立法不仅对专门焚烧厂的垃圾单一焚烧设定了严格限制,还对燃煤电厂的混合燃烧作出了规定。随着对环境问题的认识不断提高,排放限制逐步降低,越来越多的物质被纳入监管网络,在过去几十年中开发出了多种减排方法和技术。结果是出现了先进的垃圾焚烧炉,它针对烟气中的各个成分设有多个专门的处理步骤。本研究突出了一些新进展,这些进展可归纳为一个共同目标,即通过应用能在一个反应器中联合处理多种有害物质的系统,或者采用新的、更简单的路线替代以前使用的复杂路线,或者在烟气脱硫方面减少石灰石消耗量,来降低烟气处理成本。成本降低也是燃烧前对非均质垃圾进行预处理新工艺的驱动力。热解或气化用于化学预处理,而物理预处理则包括粉碎、分级和分选过程。预处理产生的燃料可在发电厂用作混合燃料或单一燃料,并且在发电厂燃烧时的条件得到更好控制,因此与传统垃圾焚烧炉中的非均质垃圾相比,排放更少。同样出于成本原因,燃煤电厂混合燃烧垃圾正大力推向市场。近期调查表明,垃圾混合燃烧对锅炉的运行性能和气态排放也可能产生有益影响。