酰胺与亚胺的直接型催化曼尼希反应。
Direct-type catalytic Mannich reactions of amides with imines.
作者信息
Saito Susumu, Tsubogo Tetsu, Kobayashi Shū
机构信息
Graduate School of Pharmaceutical Sciences, The University of Tokyo, ERATO, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
出版信息
Chem Commun (Camb). 2007 Mar 28(12):1236-7. doi: 10.1039/b618490a. Epub 2007 Feb 15.
DOI:10.1039/b618490a
PMID:17356767
Abstract
Direct-type catalytic Mannich reactions of amides with imines proceeded smoothly using barium phenoxide as a catalyst to afford the desired adducts in high yields with high anti selectivities.
摘要
使用苯氧基钡作为催化剂，酰胺与亚胺的直接型催化曼尼希反应顺利进行，以高收率和高反式选择性得到所需的加合物。
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