Catalytic carbanion reactions: formation and reaction of carbanions from ester or amide equivalents using catalytic amounts of bases.

作者信息

Kobayashi Shu, Matsubara Ryosuke

机构信息

Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO (Japan) Science Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

出版信息

Chemistry. 2009 Oct 19;15(41):10694-700. doi: 10.1002/chem.200901515.

DOI:10.1002/chem.200901515

PMID:19790210

Abstract

We describe here carbanion reactions using catalytic amounts of bases. The carbanions formed are different from conventional carbanions in which stoichiometric amounts of bases are needed for the formation. Two types of reactions using such carbanions from amide (imido) and ester equivalents are discussed.

摘要