Satoh Kotaro, Mizutani Masato, Kamigaito Masami
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan.
Chem Commun (Camb). 2007 Mar 28(12):1260-2. doi: 10.1039/b616598b. Epub 2007 Jan 11.
A new class of polymerizations was developed via metal-catalyzed C-C bond forming radical polyaddition; the monomers were designed to have a reactive C-Cl bond, which can be activated by the metal catalysts to generate a carbon radical species, along with a C=C double bond, to which the carbon radical generated from another molecule adds to form a C-C backbone polymer with an inactive C-Cl pendant.
通过金属催化的碳-碳键形成自由基聚加成反应开发了一类新型聚合反应；单体被设计成具有一个反应性碳-氯键，该键可被金属催化剂活化以产生碳自由基物种，同时具有一个碳-碳双键，来自另一个分子产生的碳自由基会加成到该双键上，从而形成具有非活性碳-氯侧基的碳-碳主链聚合物。
