钯催化富电子杂环与芳基氯化物的芳基化反应。
Palladium-catalyzed arylation of electron-rich heterocycles with aryl chlorides.
作者信息
Chiong Hendrich A, Daugulis Olafs
机构信息
Department of Chemistry, University of Houston, Houston, Texas 77204, USA.
出版信息
Org Lett. 2007 Apr 12;9(8):1449-51. doi: 10.1021/ol0702324. Epub 2007 Mar 15.
PMID:17358073
Abstract
[reaction: see text] Palladium-catalyzed C-H activation: cheap aryl chlorides can now be used for the arylation of a wide variety of electron-rich heterocycles. The key to the success of this reaction is the use of a bulky, electron-rich phosphine ligand. No copper additives are needed.
摘要
[反应：见正文] 钯催化的C-H活化：廉价的芳基氯现在可用于多种富电子杂环的芳基化反应。该反应成功的关键在于使用一种位阻大、富电子的膦配体。无需铜添加剂。
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