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[MEH-PPV/CdSe纳米复合器件的光电导特性研究]

[Investigation on the photoconductive properties of MEH-PPV/CdSe nanocomposite devices].

作者信息

Tang Ai-wei, Teng Feng, Gao Yin-hao, Jin Hui, Liang Chun-jun, Xu Zheng, Wang Yong-sheng

机构信息

Institute of Optoelectronic Technology and Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Dec;26(12):2169-72.

Abstract

Photoconductive properties of the composite devices made up of cadmium selenide nanocrystals and polymer poly[2-methoxy-5-(2'-ethylhexyloxy-p-phenylenevinylene)] (MEH-PPV) were investigated. The photocurrent action spectrum for a nanocomposite device corresponded to the absorption of MEH-PPV and CdSe nanocrystals, indicating that the absorption of the CdSe nanocrystals and MEH-PPV contributed to the photocurrent. The photocurrent was attributed to the exciton dissociation and charge transfer between the interface of CdSe nanocrystals and MEH-PPV. The photocurrent action spectra of the nanocomposite device was wider than that of the pure MEH-PPV device, and the photocurrent was enhanced in comparison with the pure MEH-PPV device due to the introduction of CdSe nanocrystals.

摘要

研究了由硒化镉纳米晶体和聚合物聚2-甲氧基-5-(2'-乙基己氧基)-对苯撑乙烯撑组成的复合器件的光电导特性。纳米复合器件的光电流作用光谱与MEH-PPV和CdSe纳米晶体的吸收相对应,表明CdSe纳米晶体和MEH-PPV的吸收对光电流有贡献。光电流归因于CdSe纳米晶体与MEH-PPV界面之间的激子解离和电荷转移。纳米复合器件的光电流作用光谱比纯MEH-PPV器件的宽,并且由于引入了CdSe纳米晶体,与纯MEH-PPV器件相比光电流增强。

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