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置于垃圾填埋场的经CCA处理的木材以及与垃圾转化能源和城市固体废弃物填埋处置相关的生命周期权衡。

CCA-treated wood disposed in landfills and life-cycle trade-offs with waste-to-energy and MSW landfill disposal.

作者信息

Jambeck Jenna, Weitz Keith, Solo-Gabriele Helena, Townsend Timothy, Thorneloe Susan

机构信息

Department of Civil Engineering, University of New Hampshire, ERG, Durham, NH, USA.

出版信息

Waste Manag. 2007;27(8):S21-8. doi: 10.1016/j.wasman.2007.02.011. Epub 2007 Apr 9.

Abstract

Chromated copper arsenate (CCA)-treated wood is a preservative treated wood construction product that grew in use in the 1970s for both residential and industrial applications. Although some countries have banned the use of the product for some applications, others have not, and the product continues to enter the waste stream from construction, demolition and remodeling projects. CCA-treated wood as a solid waste is managed in various ways throughout the world. In the US, CCA-treated wood is disposed primarily within landfills; however some of the wood is combusted in waste-to-energy (WTE) facilities. In other countries, the predominant disposal option for wood, sometimes including CCA-treated wood, is combustion for the production of energy. This paper presents an estimate of the quantity of CCA-treated wood entering the disposal stream in the US, as well as an examination of the trade-offs between landfilling and WTE combustion of CCA-treated wood through a life-cycle assessment and decision support tool (MSW DST). Based upon production statistics, the estimated life span and the phaseout of CCA-treated wood, recent disposal projections estimate the peak US disposal rate to occur in 2008, at 9.7 million m(3). CCA-treated wood, when disposed with construction and demolition (C&D) debris and municipal solid waste (MSW), has been found to increase arsenic and chromium concentrations in leachate. For this reason, and because MSW landfills are lined, MSW landfills have been recommended as a preferred disposal option over unlined C&D debris landfills. Between landfilling and WTE for the same mass of CCA-treated wood, WTE is more expensive (nearly twice the cost), but when operated in accordance with US Environmental Protection Agency (US EPA) regulations, it produces energy and does not emit fossil carbon emissions. If the wood is managed via WTE, less landfill area is required, which could be an influential trade-off in some countries. Although metals are concentrated in the ash in the WTE scenario, the MSW landfill scenario releases a greater amount of arsenic from leachate in a more dilute form. The WTE scenario releases more chromium from the ash on an annual basis. The WTE facility and subsequent ash disposal greatly concentrates the chromium, often oxidizing it to the more toxic and mobile Cr(VI) form. Elevated arsenic and chromium concentrations in the ash leachate may increase leachate management costs.

摘要

铬化砷酸铜(CCA)处理过的木材是一种经过防腐处理的木质建筑产品,在20世纪70年代开始广泛应用于住宅和工业领域。尽管一些国家已禁止在某些应用中使用该产品,但其他国家仍在使用,并且该产品继续通过建筑、拆除和翻新项目进入废物流。作为固体废物的CCA处理过的木材在世界各地有多种管理方式。在美国,CCA处理过的木材主要被填埋处理;然而,也有一些木材在垃圾转化能源(WTE)设施中燃烧。在其他国家,木材(有时包括CCA处理过的木材)的主要处置方式是燃烧以生产能源。本文估算了美国进入处置流的CCA处理过的木材数量,并通过生命周期评估和决策支持工具(MSW DST)研究了填埋和WTE燃烧CCA处理过的木材之间的权衡。根据生产统计数据、CCA处理过的木材的估计使用寿命和逐步淘汰情况,最近的处置预测估计美国处置率峰值将出现在2008年,为970万立方米。已发现,当CCA处理过的木材与建筑和拆除(C&D)废料以及城市固体废物(MSW)一起处置时,会增加渗滤液中的砷和铬浓度。因此,由于MSW填埋场有衬层,与无衬层的C&D废料填埋场相比,MSW填埋场被推荐为更优的处置选择。对于相同质量的CCA处理过的木材,WTE比填埋更昂贵(成本几乎是两倍),但按照美国环境保护局(US EPA)的规定运行时,它能产生能源且不排放化石碳。如果通过WTE管理木材,则所需填埋面积较小,这在一些国家可能是一个有影响力的权衡因素。尽管在WTE情况下金属集中在灰烬中,但MSW填埋场情况下渗滤液中会以更稀释的形式释放出更多的砷。WTE每年从灰烬中释放出更多的铬。WTE设施及后续的灰烬处置会使铬大量浓缩,通常会将其氧化成毒性更强、流动性更大的Cr(VI)形式。灰烬渗滤液中升高的砷和铬浓度可能会增加渗滤液管理成本。

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