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超声辐照加速了二茂铁基环钯亚胺在纯水中催化的铃木反应。

Ultrasonic irradiation accelerated cyclopalladated ferrocenylimines catalyzed Suzuki reaction in neat water.

作者信息

Zhang Jinli, Yang Fan, Ren Gerui, Mak Thomas C W, Song Maoping, Wu Yangjie

机构信息

Department of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou, PR China.

出版信息

Ultrason Sonochem. 2008 Feb;15(2):115-8. doi: 10.1016/j.ultsonch.2007.02.002. Epub 2007 Feb 24.

DOI:10.1016/j.ultsonch.2007.02.002
PMID:17419085
Abstract

Both conventional heating and ultrasound effect on the cyclopalladated ferrocenylimines catalyzed Suzuki reaction of phenylboronic acid with a range of arylhalides in neat water was investigated. Heterogenous reaction of electron-withdrawing arylchlorides with phenylboronic acid could also result in good yields by using Cat. 2. It was found that the ultrasonic irradiation could dramatically accelerate the Suzuki reaction to achieve comparable results.

摘要

研究了传统加热和超声对二茂铁基环钯亚胺催化的苯硼酸与一系列芳基卤化物在纯水中进行铃木反应的影响。使用催化剂2时,吸电子芳基氯与苯硼酸的多相反应也能得到良好的产率。结果发现,超声辐照能显著加速铃木反应,获得相当的结果。

相似文献

1
Ultrasonic irradiation accelerated cyclopalladated ferrocenylimines catalyzed Suzuki reaction in neat water.超声辐照加速了二茂铁基环钯亚胺在纯水中催化的铃木反应。
Ultrason Sonochem. 2008 Feb;15(2):115-8. doi: 10.1016/j.ultsonch.2007.02.002. Epub 2007 Feb 24.
2
Ultrasound effect on Suzuki reactions. 1. Synthesis of unsymmetrical biaryls.超声对铃木反应的影响。1. 不对称联芳基的合成。
Ultrason Sonochem. 2005 Jan;12(1-2):99-102. doi: 10.1016/j.ultsonch.2004.05.011.
3
Heterogeneous Pd/C-catalyzed ligand-free, room-temperature Suzuki-Miyaura coupling reactions in aqueous media.水相中多相钯碳催化的无配体室温铃木-宫浦偶联反应。
Chemistry. 2007;13(20):5937-43. doi: 10.1002/chem.200601795.
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Tandem Pd-catalyzed double C-C bond formation: effect of water.串联钯催化的双碳-碳键形成:水的影响
J Org Chem. 2009 Apr 17;74(8):3054-61. doi: 10.1021/jo900053b.
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Synthesis and catalytic activity of a poly(N,N-dialkylcarbodiimide)/palladium nanoparticle composite: a case in the Suzuki coupling reaction using microwave and conventional heating.聚(N,N-二烷基碳二亚胺)/钯纳米颗粒复合材料的合成及其催化活性:微波和传统加热条件下铃木耦合反应的实例
Chem Commun (Camb). 2004 Feb 21(4):398-9. doi: 10.1039/b313210m. Epub 2004 Jan 23.
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Palladium-catalyzed cross-coupling reactions of aryl boronic acids with aryl halides in water.钯催化芳基硼酸与芳基卤化物在水中的交叉偶联反应。
J Environ Sci (China). 2009;21 Suppl 1:S124-6. doi: 10.1016/S1001-0742(09)60054-1.
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Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed direct coupling with arylboronic acids.通过钯催化的与芳基硼酸的直接偶联反应对映选择性合成平面手性二茂铁。
J Am Chem Soc. 2013 Jan 9;135(1):86-9. doi: 10.1021/ja311082u. Epub 2012 Dec 26.
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Palladium-catalyzed decarboxylative benzylation of diphenylglycinate imines.钯催化的二苯甘氨酸亚胺的脱羧苄基化反应。
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Pd on porous glass: a versatile and easily recyclable catalyst for Suzuki and Heck reactions.负载于多孔玻璃上的钯:一种用于铃木反应和赫克反应的多功能且易于回收的催化剂。
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Ligand-free Pd/C-catalyzed Suzuki-Miyaura coupling reaction for the synthesis of heterobiaryl derivatives.无配体钯碳催化的铃木-宫浦偶联反应用于合成杂联芳基衍生物。
Chem Commun (Camb). 2007 Dec 21(47):5069-71. doi: 10.1039/b712207a. Epub 2007 Oct 2.

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