用于烯烃不对称环氧化反应的新型手性联萘衍生亚胺盐有机催化剂。
New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes.
作者信息
Page Philip C Bulman, Farah Mohamed M, Buckley Benjamin R, Blacker A John
机构信息
Department of Chemistry, Loughborough University, Loughborough, Leicestershire LE11 3TU, England.
出版信息
J Org Chem. 2007 Jun 8;72(12):4424-30. doi: 10.1021/jo070255w. Epub 2007 May 17.
PMID:17506579
Abstract
A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.
摘要
一系列联萘稠合的氮杂䓬盐已被制备出来，并用作未官能化烯烃不对称环氧化反应的有机催化剂，ee值高达84%。
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