用于烯烃环氧化的手性酮和亚胺催化剂。

Chiral ketone and iminium catalysts for olefin epoxidation.

作者信息

Wong O Andrea, Shi Yian

机构信息

Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.

出版信息

Top Curr Chem. 2010;291:201-32. doi: 10.1007/978-3-642-02815-1_16.

DOI:10.1007/978-3-642-02815-1_16

PMID:21494947

Abstract

Organo-catalyzed asymmetric epoxidation has received much attention in the past 30 years and significant progress has been made for various types of olefins. This review will cover the advancement made in the field of chiral ketone and chiral iminium salt-catalyzed epoxidations.

摘要

在过去30年里，有机催化的不对称环氧化反应备受关注，并且在各类烯烃的反应中取得了显著进展。本综述将涵盖手性酮和手性亚胺盐催化环氧化领域所取得的进展。