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M（II）-配体/钒氧化物体系（M（II）= Mn（II）、Cu（II）和Zn（II）；配体= 2,2'-联吡啶和1,10-菲咯啉）有机-无机杂化材料的水热合成及结构表征

Hydrothermal syntheses and structural characterizations of organic-inorganic hybrid materials of the M(II)-ligand/vanadium oxide system (M(II) = Mn(II), Cu(II) and Zn(II); ligand = 2,2'-bipyridine and 1,10-phenanthroline).

作者信息

Yi Zhi-Hui, Cui Xiao-Bing, Zhang Xiao, Yu Jie-Hui, Lu Jing, Xu Ji-Qing, Yang Guang-Di, Wang Tie-Gang, Yu Hai-Hui, Duan Wei-Jie

机构信息

College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023, China.

出版信息

Dalton Trans. 2007 Jun 7(21):2115-20. doi: 10.1039/b618461h. Epub 2007 Apr 3.

DOI:10.1039/b618461h
PMID:17514331
Abstract

Three organic-inorganic hybrid compounds [Mn(bpy)V(bpy)V(3)O(11)] (bpy = 2,2'-bipyridine) (1), [Cu(bpy)V(2)O(6)] (2) and [Zn(phen)3][V(2)O(6)].10H(2)O (phen = 1,10-phenanthroline) (3) have been synthesized hydrothermally. Single crystal X-ray diffraction analyses revealed that compound 1 is the first example of bpy units coordinating to different transition metals in one molecule. Compound 2 is a new isomer of [Cu(bpy)V(2)O(6)] which was named the gamma-isomer by us. In compound 3, a 2-D water sheet with big holes filled by the "naked" V(4)O(12) clusters is found.

摘要

通过水热法合成了三种有机-无机杂化化合物[Mn(bpy)V(bpy)V(3)O(11)]（bpy = 2,2'-联吡啶）（1）、[Cu(bpy)V(2)O(6)]（2）和[Zn(phen)3][V(2)O(6)].10H(2)O（phen = 1,10-菲咯啉）（3）。单晶X射线衍射分析表明，化合物1是bpy单元在一个分子中与不同过渡金属配位的首个实例。化合物2是[Cu(bpy)V(2)O(6)]的一种新异构体，我们将其命名为γ-异构体。在化合物3中，发现了一种二维水层，其中有大孔，被“裸露的”V(4)O(12)簇填充。

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