新的生物顺磁中心：产甲烷菌中八面体配位的镍（III）
New biological paramagnetic center: octahedrally coordinated nickel(III) in the methanogenic bacteria.
作者信息
Lancaster J R
出版信息
Science. 1982 Jun 18;216(4552):1324-5. doi: 10.1126/science.216.4552.1324.
Abstract
Methanobacterium bryantii was grown in medium supplemented with nickel-61, an isotope with a nuclear spin of 3/2. The appearance of nuclear hyperfine structure in the electron paramagnetic resonance spectrum of a cell extract identified a previously observed signal as nickel(III) in an environment of octahedral coordination with rhombic distortions.
摘要
布氏甲烷杆菌在添加了镍 - 61（一种核自旋为3/2的同位素）的培养基中生长。细胞提取物的电子顺磁共振谱中核超精细结构的出现，将先前观察到的信号确定为处于具有菱形畸变的八面体配位环境中的镍(III)。
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引用本文的文献
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