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超快速微波增强可逆加成-断裂链转移(RAFT)聚合:数分钟内从单体到聚合物

Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes.

作者信息

Brown Steven L, Rayner Christopher M, Graham Susan, Cooper Andrew, Rannard Steven, Perrier Sébastien

机构信息

University of Leeds, Woodhouse Lane, Leeds, UKLS2 9JT.

出版信息

Chem Commun (Camb). 2007 Jun 7(21):2145-7. doi: 10.1039/b703386a. Epub 2007 Apr 30.

Abstract

Microwave mediated RAFT polymerization leads to ultra-fast polymerizations, whilst keeping excellent control over molecular weights and molecular weight distributions; this is the first example of such a dramatic effect of microwaves on living radical polymerization kinetics, and it shows the potential for chemists to produce very well controlled polymers in a matter of minutes.

摘要

微波介导的可逆加成-断裂链转移(RAFT)聚合反应能够实现超快速聚合,同时对分子量和分子量分布保持出色的控制;这是微波对活性自由基聚合动力学产生如此显著影响的首个实例,它展示了化学家在数分钟内制备出控制良好的聚合物的潜力。

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