Brown Steven L, Rayner Christopher M, Graham Susan, Cooper Andrew, Rannard Steven, Perrier Sébastien
University of Leeds, Woodhouse Lane, Leeds, UKLS2 9JT.
Chem Commun (Camb). 2007 Jun 7(21):2145-7. doi: 10.1039/b703386a. Epub 2007 Apr 30.
Microwave mediated RAFT polymerization leads to ultra-fast polymerizations, whilst keeping excellent control over molecular weights and molecular weight distributions; this is the first example of such a dramatic effect of microwaves on living radical polymerization kinetics, and it shows the potential for chemists to produce very well controlled polymers in a matter of minutes.
微波介导的可逆加成-断裂链转移（RAFT）聚合反应能够实现超快速聚合，同时对分子量和分子量分布保持出色的控制；这是微波对活性自由基聚合动力学产生如此显著影响的首个实例，它展示了化学家在数分钟内制备出控制良好的聚合物的潜力。
