Venkatasubbaiah Krishnan, Nowik Israel, Herber Rolfe H, Jäkle Frieder
Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.
Chem Commun (Camb). 2007 Jun 7(21):2154-6. doi: 10.1039/b701807j. Epub 2007 May 1.
The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1(+)PF(6) and further confirmed from the strong complexation of MeCN to the dication in 2(2+)(I(3))(2).
通过对混合价阳离子1(+)PF(6)的X射线结构参数的研究可以明显看出，二硼二茂铁1中硼的路易斯酸性通过铁原子的氧化而得到显著增强，并且在2(2+)(I(3))(2)中乙腈与二价阳离子的强络合作用进一步证实了这一点。
