非纳米金催化仲胺有氧氧化生成亚胺。
Non-nanogold catalyzed aerobic oxidation of secondary amines to imines.
作者信息
Zhu Bolin, Angelici Robert J
机构信息
Ames Laboratory and Department of Chemistry, Iowa State University, Ames, IA 50011-3111, USA.
出版信息
Chem Commun (Camb). 2007 Jun 7(21):2157-9. doi: 10.1039/b700555e. Epub 2007 May 1.
DOI:10.1039/b700555e
PMID:17520121
Abstract
Bulk gold powder (approximately 10(3) nm particle size) is a highly active catalyst for the oxidative dehydrogenation of secondary amines to imines under the mild conditions of 1 atm O2 and 60-100 degrees C.
摘要
散装金粉（粒径约为10³纳米）是一种高活性催化剂，可在1个大气压氧气和60 - 100摄氏度的温和条件下，将仲胺氧化脱氢生成亚胺。
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