在环境条件下，直接温和的钯催化醇和胺的有氧氧化合成亚胺。
Direct and mild palladium-catalyzed aerobic oxidative synthesis of imines from alcohols and amines under ambient conditions.
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China.
出版信息
Chem Commun (Camb). 2011 Oct 14;47(38):10833-5. doi: 10.1039/c1cc14242a. Epub 2011 Aug 25.
PMID:21869963
Abstract
By ligand, TEMPO, and base screening, we developed a mild and green one-pot imine synthesis from alcohols and amines via a low-loading palladium-catalyzed tandem aerobic alcohol oxidation-dehydrative condensation reaction that can be readily carried out in open air at room temperature.
摘要
通过配体、TEMPO 和碱的筛选，我们开发了一种温和、绿色的从醇和胺一锅法制备亚胺的方法，该方法通过低负载量钯催化的串联有氧醇氧化-脱水缩合反应实现，可在室温下于开放空气中方便地进行。
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