影响含氮杂环上硫化物不对称氧化选择性的因素。
Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles.
作者信息
Seenivasaperumal Muthu, Federsel Hans-Jürgen, Ertan Anne, Szabó Kálmán J
机构信息
Stockholm University, Arrhenius Laboratory, Department of Organic Chemistry, Sweden.
出版信息
Chem Commun (Camb). 2007 Jun 7(21):2187-9. doi: 10.1039/b700860k. Epub 2007 Mar 2.
DOI:10.1039/b700860k
PMID:17520131
Abstract
Asymmetric oxidation of heterocyclic sulfides, including imidazole, benzimidazole, indole and pyrimidine derivatives, were studied using a tartrate/Ti((i)OPr)4 catalyst system.
摘要
使用酒石酸盐/Ti((i)OPr)4催化剂体系研究了包括咪唑、苯并咪唑、吲哚和嘧啶衍生物在内的杂环硫化物的不对称氧化反应。
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