Garcia M A, Merino J M, Fernández Pinel E, Quesada A, de la Venta J, Ruíz González M L, Castro G R, Crespo P, Llopis J, González-Calbet J M, Hernando A
Instituto de Magnetismo Aplicado (UCM-ADIF-CSIC), P.O. Box 155, 28230 Las Rozas, Madrid, Spain.
Nano Lett. 2007 Jun;7(6):1489-94. doi: 10.1021/nl070198m. Epub 2007 May 24.
We experimentally show that it is possible to induce room-temperature ferromagnetic-like behavior in ZnO nanoparticles without doping with magnetic impurities but simply inducing an alteration of their electronic configuration. Capping ZnO nanoparticles ( approximately 10 nm size) with different organic molecules produces an alteration of their electronic configuration that depends on the particular molecule, as evidenced by photoluminescence and X-ray absorption spectroscopies and altering their magnetic properties that varies from diamagnetic to ferromagnetic-like behavior.
我们通过实验表明,在不掺杂磁性杂质的情况下,仅通过改变氧化锌纳米颗粒的电子构型,就有可能诱导其呈现室温下类似铁磁的行为。用不同有机分子包覆氧化锌纳米颗粒(尺寸约为10纳米)会导致其电子构型发生改变,这种改变取决于具体的分子,光致发光和X射线吸收光谱证明了这一点,同时这种改变还会使其磁性能发生变化,从抗磁性转变为类似铁磁的行为。