通过钌催化 N-乙烯基酰胺与烯烃或炔烃的共低聚反应实现烯酰胺和二烯酰胺的区域和立体选择性合成。 - Suppr

Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

作者信息

Tsujita Hiroshi, Ura Yasuyuki, Matsuki Shingo, Wada Kenji, Mitsudo Take-aki, Kondo Teruyuki

机构信息

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Angew Chem Int Ed Engl. 2007;46(27):5160-3. doi: 10.1002/anie.200701356.

DOI:10.1002/anie.200701356

PMID:17526039

Abstract

摘要

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Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

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Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

作者信息

Tsujita Hiroshi, Ura Yasuyuki, Matsuki Shingo, Wada Kenji, Mitsudo Take-aki, Kondo Teruyuki

机构信息

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.

出版信息

Angew Chem Int Ed Engl. 2007;46(27):5160-3. doi: 10.1002/anie.200701356.

DOI:10.1002/anie.200701356

PMID:17526039

Abstract

摘要

相似文献

Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

Angew Chem Int Ed Engl. 2007;46(27):5160-3. doi: 10.1002/anie.200701356.

Ru-catalyzed anti-Markovnikov addition of amides to alkynes: a regio- and stereoselective synthesis of enamides.

Angew Chem Int Ed Engl. 2005 Jun 27;44(26):4042-5. doi: 10.1002/anie.200462844.

Synthesis of beta,beta-disubstituted vinyl boronates via the ruthenium-catalyzed Alder ene reaction of borylated alkynes and alkenes.

J Am Chem Soc. 2005 Mar 16;127(10):3252-3. doi: 10.1021/ja0424629.

Synthesis of secondary enamides by ruthenium-catalyzed selective addition of amides to terminal alkynes.

Angew Chem Int Ed Engl. 2008;47(44):8492-5. doi: 10.1002/anie.200803068.

Ruthenium-catalyzed [2 + 2] cycloadditions of bicyclic alkenes with alkynyl phosphonates.

J Org Chem. 2009 Aug 7;74(15):5762-5. doi: 10.1021/jo9010206.

Regio- and stereoselective synthesis of 2-amino-1,3-diene derivatives by ruthenium-catalyzed coupling of ynamides and ethylene.

Org Lett. 2011 May 20;13(10):2718-21. doi: 10.1021/ol200812y. Epub 2011 Apr 21.

Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes.

Org Lett. 2013 Jan 4;15(1):136-9. doi: 10.1021/ol303159h. Epub 2012 Dec 12.

Ruthenium-catalyzed cycloisomerization of cis-3-en-1-ynes to cyclopentadiene and related derivatives through a 1,5-sigmatropic hydrogen shift of ruthenium-vinylidene intermediates.

J Am Chem Soc. 2005 Aug 24;127(33):11606-7. doi: 10.1021/ja053674o.

Platinum(II)-catalyzed cyclizations forming quaternary carbon centers, using enesulfonamides, enecarbamates, or enamides as nucleophiles.

Org Lett. 2007 Jan 18;9(2):367-70. doi: 10.1021/ol062939g.

Mechanistic investigation of the Ru-catalyzed hydroamidation of terminal alkynes.

J Am Chem Soc. 2011 May 18;133(19):7428-49. doi: 10.1021/ja111389r. Epub 2011 Apr 26.

引用本文的文献

Computational study of the mechanism and selectivity of ruthenium-catalyzed hydroamidations of terminal alkynes.

Chem Sci. 2015 Apr 1;6(4):2532-2552. doi: 10.1039/c4sc03906h. Epub 2015 Feb 18.

Diastereoselective carbocyclization of 1,6-heptadienes triggered by rhodium-catalyzed activation of an olefinic C-H bond.

Angew Chem Int Ed Engl. 2014 Apr 14;53(16):4209-12. doi: 10.1002/anie.201400080. Epub 2014 Mar 14.

Reactivity and selectivity in hydrovinylation of strained alkenes.

J Org Chem. 2010 Nov 19;75(22):7636-43. doi: 10.1021/jo1015135. Epub 2010 Oct 21.

Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

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Regio- and stereoselective synthesis of enamides and dienamides by ruthenium-catalyzed co-oligomerization of N-vinylamides with alkenes or alkynes.

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