伯吉斯试剂与硫醇的意外反应：对称二硫化物的合成
Unexpected reactivity of the burgess reagent with thiols: synthesis of symmetrical disulfides.
作者信息
Banfield Scott C, Omori Alvaro Takeo, Leisch Hannes, Hudlicky Tomas
机构信息
Department of Chemistry and Center for Biotechnology, Brock University, 500 Glenridge Avenue, St. Catharines, Canada L2S 3A1.
出版信息
J Org Chem. 2007 Jun 22;72(13):4989-92. doi: 10.1021/jo070099t. Epub 2007 Jun 1.
PMID:17539682
Abstract
Reaction of the Burgess reagent with a series of aliphatic and aromatic thiols led to the corresponding symmetrical disulfides in high yields. No olefins were detected in the reactions of aliphatic thiols.
摘要
伯吉斯试剂与一系列脂肪族和芳香族硫醇反应，以高收率生成了相应的对称二硫化物。在脂肪族硫醇的反应中未检测到烯烃。
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