Gerhardt Ilja, Wrigge Gert, Agio Mario, Bushev Pavel, Zumofen Gert, Sandoghdar Vahid
Laboratory of Physical Chemistry, ETH Zurich, Zurich, Switzerland.
Opt Lett. 2007 Jun 1;32(11):1420-2. doi: 10.1364/ol.32.001420.
We present scanning near-field extinction spectra of single molecules embedded in a solid matrix. By varying the tip-molecule separation, we modify the line shape of the spectra, demonstrating the coherent nature of the interaction between the incident laser light and the excited state of the molecule. We compare the measured data with the outcome of numerical calculations and find a very good agreement.
我们展示了嵌入固体基质中的单分子的扫描近场消光光谱。通过改变针尖与分子之间的距离,我们改变了光谱的线形,证明了入射激光与分子激发态之间相互作用的相干性质。我们将测量数据与数值计算结果进行比较,发现两者非常吻合。