关于海盗号气相色谱 - 质谱仪检测有机物的能力。
On the ability of the Viking gas chromatograph-mass spectrometer to detect organic matter.
作者信息
Biemann Klaus
机构信息
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
出版信息
Proc Natl Acad Sci U S A. 2007 Jun 19;104(25):10310-3. doi: 10.1073/pnas.0703732104. Epub 2007 Jun 4.
Abstract
A recent paper by Navarro-Gonzalez et al. [Navarro-Gonzalez R, Navarro KF, de la Rosa J, Iniguez E, Molina P, Miranda LD, Morales P, Cienfuegos E, Coll P, Raulin F, et al. (2006) Proc Natl Acad Sci USA 103:16089-16094] claims to show that the Viking GCMS (gas chromatograph-mass spectrometer) experiment, which carried out a search for organic matter at the surface of Mars in 1976, "may have been blind to low levels of organics." To rebut this assertion, the Viking experiment, test data, and results on Mars are reviewed, and the fallacies in the design, execution, and interpretation of the new experiments presented by Navarro-Gonzalez et al. are critically examined.
摘要
纳瓦罗 - 冈萨雷斯等人近期发表的一篇论文[纳瓦罗 - 冈萨雷斯R，纳瓦罗KF，德拉罗萨J，伊尼格斯E，莫利纳P，米兰达LD，莫拉莱斯P，西恩富戈斯E，科尔P，劳兰F等（2006年）《美国国家科学院院刊》103:16089 - 16094]声称表明，1976年在火星表面进行有机物搜索的海盗号气相色谱 - 质谱仪（GCMS）实验“可能对低含量有机物视而不见”。为反驳这一断言，本文回顾了海盗号实验、测试数据以及在火星上的结果，并对纳瓦罗 - 冈萨雷斯等人所展示新实验在设计、实施和解读方面的谬误进行了批判性审视。
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本文引用的文献
1
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Science. 1976 Sep 24;193(4259):1247-9. doi: 10.1126/science.193.4259.1247.
2
Inorganic analyses of martian surface samples at the viking landing sites.对维京着陆点火星表面样本的无机分析。
Science. 1976 Dec 11;194(4271):1283-8. doi: 10.1126/science.194.4271.1283.
3
The viking biological investigation: preliminary results.维京生物调查：初步结果。
Science. 1976 Oct 1;194(4260):99-105. doi: 10.1126/science.194.4260.99.
4
Search for organic and volatile inorganic compounds in two surface samples from the chryse planitia region of Mars.在火星克里斯平原地区的两个地表样本中寻找有机化合物和挥发性无机化合物。
Science. 1976 Oct 1;194(4260):72-6. doi: 10.1126/science.194.4260.72.
5
Mars: is the surface colored by carbon suboxide?火星：是表面的颜色由碳亚氧化物造成的吗？
Science. 1969 Nov 28;166(3909):1141-2. doi: 10.1126/science.166.3909.1141.
6
Aromatic hydrocarbons in the murchison meteorite.默奇森陨石中的芳烃。
Science. 1971 Jul 16;173(3993):237-9. doi: 10.1126/science.173.3993.237.
7
Gas chromatographic column for the viking 1975 molecular analysis experiment.用于 Viking 1975 分子分析实验的气相色谱柱。
Science. 1975 Jul 18;189(4198):215-6. doi: 10.1126/science.189.4198.215.
8
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9
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10
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Science. 1969 May 30;164(3883):1054-6. doi: 10.1126/science.164.3883.1054.
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