Zn mobility and geochemistry in surface sulfide mining soils from SE Spain.

The extraction of metallic minerals and the mineral dressing operations in concentrators produced a high impact in soils and sediments. Heavy metals in soils constitute a high risk of pollution, not only for mining areas, but also for agriculture and villages placed in subsidiary areas. This research has been focused on the assessment of the real environmental and health hazards of Zn in relation to geochemistry and metal mobility in surface soils from a mining area in SE Spain, under semiarid weather conditions. Mineralogy of the studied soils revealed major presence of quartz, but also of other silicates, sulfates, carbonates, and sulfides. Regarding Zn minerals, the presence of sphalerite as the main Zn sulfide, and of goslarite as Zn sulfate, and of smithsonite as Zn carbonate should be highlighted. Soil pH ranged between 4.4 and 4.9 and the electrical conductivity between 55 and 85 microS/cm. By using the sequential extraction procedure, the achieved results show that zinc is not only mainly associated to primary but also to secondary sulfides. Total concentration of the non-available fractions rises up to 98.45% of total Zn in the studied soils. On the other hand, available Zn fraction did not exceed more than 1.55% in percentage and less than 2000 ppm in absolute terms, and when referred to more easily available fraction (water-soluble and exchangeable fractions), these values are not more than 0.44% and then 800 ppm. Therefore, although there is a significant pollution level in this area, immediate hazard for the environment can be assessed as moderate. Finally it should be highlighted that these surface soils have undergone concentration processes of sphalerite, whose mechanisms should be related to the ascending flow of capillary water and the dragging of sphalerite crystals and Zn salts by electrokinetic and colloidal processes These processes seem to occur based on environmental pollution by wind and water erosion, and therefore directly associated to environmental pollution and risks by free metals.