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Targeted synthesis of mu-oxo divanadium(V) compounds with asymmetry in coordination environments.

作者信息

Chatterjee Pabitra Baran, Kundu Nabanita, Bhattacharya Subhojit, Choi Ki-Young, Endo Akira, Chaudhury Muktimoy

机构信息

Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 700 032, India.

出版信息

Inorg Chem. 2007 Jul 9;46(14):5483-5. doi: 10.1021/ic700858g. Epub 2007 Jun 12.

DOI:10.1021/ic700858g
PMID:17564437
Abstract

Isovalent mu-oxo divanadium(V) compounds [L1VO(mu-O)VO(salen)] (1) and its bromo derivative [L2VO(mu-O)VO(salen)].CH3CN (2) (both H2L1 and H2L2 are tridentate dithiocarbazate-based ONS ligands) with ligands providing donor set and coordination number asymmetry in tandem have been synthesized for the first time; confirmations in favor of these unsymmetrical molecular structures have come from single-crystal X-ray diffraction analysis, as well as from NMR (both 1H and 51V) spectroscopy.

摘要

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