Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 700032, India.
Inorg Chem. 2012 Jul 16;51(14):7454-6. doi: 10.1021/ic301054r. Epub 2012 Jul 3.
Heterobimetallic compounds [L(1)OV(V)═O→Fe(metsalophen)(H(2)O)] (1) and [L(2)OV(V)═O→Fe(metsalophen)(H(2)O)]CH(3)CN (2), where H(2)L(1) and H(2)L(2) are tridentate dithiocarbazate-based Schiff base ligands, containing a discrete V(V)-μ-O-Fe(III) angular core have been synthesized for the first time through a targeted synthesis route: confirmation in favor of such a heterobimetallic core structure has come from single-crystal X-ray diffraction analysis and electrospray ionization mass spectrometry.
偕二氧钒(V)合铁(III)的异双核配合物 [L(1)OV(V)═O→Fe(metsalophen)(H(2)O)] (1) 和 [L(2)OV(V)═O→Fe(metsalophen)(H(2)O)]CH(3)CN (2)，其中 H(2)L(1)和 H(2)L(2) 是基于三齿二硫代氨基甲酸盐的希夫碱配体，含有离散的 V(V)-μ-O-Fe(III)角型核，通过有针对性的合成路线首次合成：单晶 X 射线衍射分析和电喷雾质谱分析支持了这种异双核核心结构的确认。
