碘化亚铜介导的芳基卤化物与肟的交叉偶联反应：直接合成O-芳基肟
CuI-mediated cross-coupling of aryl halides with oximes: a direct access to O-aryloximes.
作者信息
De Prithwiraj, Pandurangan Komala, Maitra Uday, Wailes Steve
机构信息
Department of Organic Chemistry, Indian Institute of Science, Bangalore, India.
出版信息
Org Lett. 2007 Jul 19;9(15):2767-70. doi: 10.1021/ol0709578. Epub 2007 Jun 20.
PMID:17580882
Abstract
The first Cu-catalyzed cross-coupling of aromatic oximes and haloarenes is reported. This one-step formation of the =N-O-Ar linkage gives access to a range of oxime ethers in good to moderate yields.
摘要
据报道，首次实现了铜催化的芳香族肟与卤代芳烃的交叉偶联反应。通过一步反应形成=N-O-Ar键，能够以良好至中等的产率得到一系列肟醚。
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