Rebelo Luís Paulo N, Lopes José N Canongia, Esperança José M S S, Guedes Henrique J R, Łachwa Joanna, Najdanovic-Visak Vesna, Visak Zoran P
Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Av. República, Apartado 127, 2780-901 Oeiras, Portugal.
Acc Chem Res. 2007 Nov;40(11):1114-21. doi: 10.1021/ar7000556. Epub 2007 Jul 11.
The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
利用分子视角分析了离子液体迷人而复杂的行为，该视角强调了离子液体的双重二元性质，即阳离子和阴离子的存在形成了高电荷密度和低电荷密度区域。我们的工作跨越了5年的研究，涵盖了离子液体及其混合物和溶液的汽化、液-液分层、凝固和热物理行为等不同主题，涉及液相、气相和固相。
