Kang Shou-fang, Li Jun-hua, Fu Li-xin, Hao Zheng-ping
Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.
Huan Jing Ke Xue. 2007 May;28(5):958-62.
Cu-Mg-Al hydrotalcite mixed oxide was prepared by co-precipitation. The mixed oxide and its procurer were characterized by XRD. NO, storage performance and decomposition of the stored NO, over the catalyst were investigated by NO, storage experiment at constant temperature, temperature programmed desorption (TPD) and temperature programmed surface reaction (TPSR), respectively. The results indicate that Cu-Mg-Al hydrotalcite mixed oxide has a good performance of NO, storage. The formed nitrate can be decomposed to gaseous NOx rapidly in the investigated temperature range of 160-360 degrees C, and a small amount of gaseous NO, can be reduced by C3 H6 with increasing the concentration of C3 H6 in the inlet gas.
采用共沉淀法制备了Cu-Mg-Al水滑石混合氧化物。通过XRD对混合氧化物及其前驱体进行了表征。分别通过恒温NO储存实验、程序升温脱附(TPD)和程序升温表面反应(TPSR)研究了该催化剂上NO的储存性能以及储存的NO的分解情况。结果表明,Cu-Mg-Al水滑石混合氧化物具有良好的NO储存性能。在160-360℃的研究温度范围内,生成的硝酸盐能够迅速分解为气态氮氧化物,并且随着进气中C3H6浓度的增加,少量气态NO能够被C3H6还原。