Gao Suo, Liu Hai-Yang, Wang Yue-Hu, He Hong-Ping, Wang Jun-Song, Di Ying-Tong, Li Chun-Shun, Fang Xin, Hao Xiao-Jiang
State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650204, Yunnan, People's Republic of China.
Org Lett. 2007 Aug 16;9(17):3453-5. doi: 10.1021/ol701501p. Epub 2007 Jul 18.
Lathyranone A (1), a novel diterpenoid with a rearrangement skeleton, along with a known diterpenoid, Euphorbia factor L(11) (2), was isolated from the seeds of Euphorbia lathyris. The structure and relative stereochemistry of 1 were elucidated by extensive spectroscopic analysis. A possible biosynthetic pathway for lathyranone A (1) was proposed.
拉替拉酮A（1）是一种具有重排骨架的新型二萜类化合物，与一种已知的二萜类化合物大戟因子L（11）（2）一起，从续随子种子中分离得到。通过广泛的光谱分析阐明了1的结构和相对立体化学。提出了拉替拉酮A（1）可能的生物合成途径。
