Ma Jian-feng, Liu Jin-song, Zhang Da-feng, Wang Si-qian, Wang Wei, Chao Yong-lie
Department of Prosthetics, School and Hospital of Stomatology, Wenzhou Medical College, Wenzhou 325027, Zhejiang Province, China.
Shanghai Kou Qiang Yi Xue. 2007 Jun;16(3):307-10.
The aim of this study was to investigate the corrosion behavior of three metal materials for dental use (Co-Cr alloy, Ni-Cr alloy, titanium) by measurement of their surface roughness after soaked in artificial saliva with two different pH values.
Standard samples were casted respectively from 3 different alloys and grided into the same roughness .Then the samples were exposed to artificial saliva with two different pH values. After three months,the surface roughness of the samples was tested, and the microstructure of surfaces was studied by metalloscope. The data were analyzed with SPSS11.0 software package for one-way ANOVA and t test.
There was significant difference in surface roughness of three alloys after exposed to artificial saliva with pH5.6. The surface roughness values of three alloys were listed as follows: Ni-Cr alloy>Co-Cr alloy >titanium(P<0.01). When exposed to artificial saliva with pH7.0, Ni-Cr alloy was found rougher than Co-Cr alloy and titanium(P<0.01), while there was no significant difference in roughness between Co-Cr alloy and titanium(P>0.05).Ni-Cr alloy and Co-Cr alloy soaked in artificial saliva with pH5.6 were found rougher than the same material in artificial saliva with pH7.0(P<0.01).The microstructure of the samples' surface verified the results.
Titanium was stable not only in neutral environment but also in acid environment. The corrosion resistance of Co-Cr alloy and Ni-Cr alloy was superior in neutral environment than in acid environment. The corrosion resistance of the three alloys was: Titanium >Co-Cr alloy >Ni-Cr alloy.
本研究旨在通过测量三种牙科用金属材料(钴铬合金、镍铬合金、钛)在两种不同pH值的人工唾液中浸泡后的表面粗糙度,来研究其腐蚀行为。
分别用三种不同合金铸造标准样品,并打磨至相同粗糙度。然后将样品置于两种不同pH值的人工唾液中。三个月后,测试样品的表面粗糙度,并用金相显微镜研究表面微观结构。数据用SPSS11.0软件包进行单因素方差分析和t检验。
三种合金在pH5.6的人工唾液中浸泡后,表面粗糙度有显著差异。三种合金的表面粗糙度值如下:镍铬合金>钴铬合金>钛(P<0.01)。在pH7.0的人工唾液中浸泡时,发现镍铬合金比钴铬合金和钛更粗糙(P<0.01),而钴铬合金和钛之间的粗糙度没有显著差异(P>0.05)。发现浸泡在pH5.6人工唾液中的镍铬合金和钴铬合金比浸泡在pH7.0人工唾液中的相同材料更粗糙(P<0.01)。样品表面的微观结构证实了该结果。
钛不仅在中性环境中稳定,在酸性环境中也稳定。钴铬合金和镍铬合金在中性环境中的耐腐蚀性优于酸性环境。三种合金的耐腐蚀性为:钛>钴铬合金>镍铬合金。