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[不同pH值人工唾液中Cr合金耐腐蚀性的研究]

[Study on the corrosion resistance of Cr ahoy in the artificial saliva with different pH value].

作者信息

Su Run-Gang, Li Chun-Hua, Qian Ye

机构信息

Dept. of Stomatology, Benxi Central Hospital, Benxi 117000, China.

出版信息

Hua Xi Kou Qiang Yi Xue Za Zhi. 2010 Feb;28(1):34-7.

Abstract

OBJECTIVE

To study the effect on the corrosion resistance of Cr alloy in the artificial saliva with different pH value in vitro.

METHODS

Compared to Ti alloy, electrochemical technique was used to measure the electric potential of corrosion (E(corr)), current density of corrosion (I(corr)) Cr alloy in the artificial saliva with different pH value. The corrosion and corrosion resistance mechanism on Cr alloy in the artificial saliva with different pH value had been investigated by the EIS curves.

RESULTS

The corrosion resistance of Co-Cr alloy was better than Ti alloy. The value of I(corr) was lower and the value of R(p) was larger than Ti alloy. The corrosion resistance of Ni-Cr alloy was worse than Ti alloy. The value of I(corr) was larger and the value of R(p) was lower than Ti alloy. The pH value in the artificial saliva was decreased, the I(corr) value of three types of alloy increased, the R(p) value of three types of alloy decreased. But the changes of Co-Cr alloy was smaller than that of Ti alloy or Ni-Cr alloy.

CONCLUSION

The corrosion resistance of Co-Cr alloy was superior to that of Ni-Cr alloy and Ti alloy. In the acid artificial saliva, the corrosion resistance of three types of alloy descended evidently.

摘要

目的

体外研究不同pH值人工唾液中Cr合金的耐腐蚀性能。

方法

采用电化学技术,以钛合金为对照,测量不同pH值人工唾液中Cr合金的腐蚀电位(E(corr))、腐蚀电流密度(I(corr))。通过电化学阻抗谱(EIS)曲线研究不同pH值人工唾液中Cr合金的腐蚀及耐腐蚀机制。

结果

钴铬合金的耐腐蚀性优于钛合金,其I(corr)值较低,R(p)值高于钛合金。镍铬合金的耐腐蚀性比钛合金差,其I(corr)值较大,R(p)值低于钛合金。人工唾液pH值降低时,三种合金的I(corr)值均升高,R(p)值均降低,但钴铬合金的变化幅度小于钛合金或镍铬合金。

结论

钴铬合金的耐腐蚀性优于镍铬合金和钛合金。在酸性人工唾液中,三种合金的耐腐蚀性均明显下降。

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