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黄河中下游表层沉积物中有机氯农药的分布

[Distribution of organochlorine pesticides in surface sediments from the middle and lower reaches of the Yellow River].

作者信息

Sun Jian-Hui, Wang Guo-Liang, Zhang Gan, Li Jun, Chai Yan, Wang Jing-Zhi, Duan Yan-Pei

机构信息

State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of sciences, Guangzhou 510640, China.

出版信息

Huan Jing Ke Xue. 2007 Jun;28(6):1332-7.

Abstract

Organochlorine pesticides (OCPs) in twenty-three sediment samples from the middle and lower reaches of the Yellow River were analyzed by GC-ECD. The OCPs detected were comprised mainly of HCHs, DDTs, hexachlorobenzene, chlordane, etc. The range of total OCPs concentration was 0.35 - 22.92 ng/g. The concentrations of HCHs and DDTs were much higher than other compounds and varied from 0.05 - 5.03 ng/g and 0.09 - 12.88 ng/g, respectively. Contamination level of OCPs in sediment increased from middle to lower reaches along the Yellow River. The distribution of total OCPs in main tributaries followed the sequence: Xinmang River > Jindi River > Si River > Yiluo River > Qin River. The Yellow River had a much higher concentration of HCHs than Hai River, the Pearl River, the Yangtze River and Huangpu River, and almost the same concentration of DDTs as other rivers except Hai River. The contamination of OCPs in the sediments from the middle and lower reaches of the Yellow River derived mainly from industrial contamination in riverbasim, the inflow of the main tributaries and the residues of organochlorine pesticides widely used for a long-term and the aged and weathered agricultural soils.

摘要

采用气相色谱 - 电子捕获检测器(GC - ECD)对黄河中下游23个沉积物样品中的有机氯农药(OCPs)进行了分析。检测到的OCPs主要包括六氯环己烷(HCHs)、滴滴涕(DDTs)、六氯苯、氯丹等。OCPs总浓度范围为0.35 - 22.92 ng/g。HCHs和DDTs的浓度远高于其他化合物,分别在0.05 - 5.03 ng/g和0.09 - 12.88 ng/g之间变化。黄河沉积物中OCPs的污染水平沿黄河从上游到下游逐渐升高。主要支流中OCPs总量的分布顺序为:蟒河>沁河>泗河>伊洛河>渭河。黄河中HCHs的浓度远高于海河、珠江、长江和黄浦江,DDTs的浓度与除海河外的其他河流几乎相同。黄河中下游沉积物中OCPs的污染主要源于流域内的工业污染、主要支流的汇入以及长期广泛使用的有机氯农药在老化和风化农业土壤中的残留。

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