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淮河上游有机氯农药(OCPs)残留。

Residues of organochlorine pesticides (OCPs) in upper reach of the Huaihe River, East China.

机构信息

Key Laboratory of Yellow River and Huai River Water Environment and Pollution Control, Ministry of Education, Henan Key Laboratory for Environmental Pollution Control, Xinxiang, Henan 453007, PR China.

出版信息

Ecotoxicol Environ Saf. 2011 Nov;74(8):2252-9. doi: 10.1016/j.ecoenv.2011.08.001. Epub 2011 Aug 26.

Abstract

Residues of HCHs and DDTs in surface water and suspended particulate matter (SPM) from upper reach of the Huaihe River, East China, were investigated. Levels of total HCHs (∑HCH) and total DDTs (∑DDT) in water detected by GC-ECD ranged from 0.85 to 12.77 ng L⁻¹ and from 3.54 to 33.59 ng L⁻¹, respectively. According to European and America water quality guidelines, HCHs were within safe levels while DDT would pose adverse biological effects. Distribution of OCPs in water indicated that input of tributaries was important factor for the Huaihe River. For OCPs in SPM, concentrations varied from 1.01 to 25.22 ng g⁻¹ for ∑HCH and not detected to 4.74 ng g⁻¹ for ∑DDT. Compared with sediment quality guidelines, HCHs and DDTs might have an ecological risk. The main reason for OCPs residues in the Huaihe River was usage of lindane and technical DDT. Furthermore, composition of DDTs reflected fresh inputs of dicofol mixture in some sites.

摘要

本研究调查了中国东部淮河流域上游地表水中的六六六(HCHs)和滴滴涕(DDTs)残留情况。GC-ECD 检测到的水中总 HCH(∑HCH)和总 DDT(∑DDT)的浓度范围分别为 0.85-12.77ng/L 和 3.54-33.59ng/L。根据欧美水质准则,HCHs 在安全水平内,而 DDT 可能会产生不良的生物影响。水中有机氯农药(OCPs)的分布表明,支流的输入是淮河流域的重要因素。对于 SPM 中的 OCPs,∑HCH 的浓度范围为 1.01-25.22ng/g,∑DDT 未检出至 4.74ng/g。与沉积物质量准则相比,HCHs 和 DDTs 可能具有生态风险。淮河流域 OCPs 残留的主要原因是林丹和滴滴涕的使用。此外,在一些地点,DDTs 的组成反映了三氯杀螨醇混合物的新鲜输入。

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