Poole Colin F, Poole Salwa K
Department of Chemistry, Wayne State University, Detroit, MI 48202, USA.
J Chromatogr A. 2008 Mar 14;1184(1-2):254-80. doi: 10.1016/j.chroma.2007.07.028. Epub 2007 Jul 21.
The application of the solvation parameter model for the classification of wall-coated open-tubular columns for gas chromatography is reviewed. A system constants database for 50 wall-coated open-tubular columns at five equally spaced temperatures between 60 and 140 degrees C is constructed and statistical and chemometric techniques used to identify stationary phases with equivalent selectivity, the effect of monomer chemistry on selectivity, and the selection of stationary phases for method development. The system constants database contains examples of virtually all commercially available common stationary phases.
综述了溶剂化参数模型在气相色谱壁涂开管柱分类中的应用。构建了一个包含50根壁涂开管柱在60至140摄氏度之间五个等间隔温度下的系统常数数据库，并运用统计和化学计量技术来识别具有等效选择性的固定相、单体化学对选择性的影响以及用于方法开发的固定相选择。该系统常数数据库包含了几乎所有市售常见固定相的示例。
