Achilias D S, Roupakias C, Megalokonomos P, Lappas A A, Antonakou Epsilon V
Laboratory of Organic Chemical Technology, Department of Chemistry, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece.
J Hazard Mater. 2007 Nov 19;149(3):536-42. doi: 10.1016/j.jhazmat.2007.06.076. Epub 2007 Jun 29.
The recycling of either model polymers or waste products based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) or polypropylene (PP) is examined using the dissolution/reprecipitation method, as well as pyrolysis. In the first technique, different solvents/non-solvents were examined at different weight percent amounts and temperatures using as raw material both model polymers and commercial products (packaging film, bags, pipes, food-retail outlets). The recovery of polymer in every case was greater than 90%. FT-IR spectra and tensile mechanical properties of the samples before and after recycling were measured. Furthermore, catalytic pyrolysis was carried out in a laboratory fixed bed reactor with an FCC catalyst using again model polymers and waste products as raw materials. Analysis of the derived gases and oils showed that pyrolysis gave a mainly aliphatic composition consisting of a series of hydrocarbons (alkanes and alkenes), with a great potential to be recycled back into the petrochemical industry as a feedstock for the production of new plastics or refined fuels.
采用溶解/再沉淀法以及热解方法,对基于低密度聚乙烯(LDPE)、高密度聚乙烯(HDPE)或聚丙烯(PP)的模型聚合物或废品的回收利用进行了研究。在第一种技术中,以模型聚合物和商业产品(包装薄膜、袋子、管道、食品零售店)作为原材料,在不同的重量百分比和温度下,对不同的溶剂/非溶剂进行了研究。在每种情况下,聚合物的回收率均大于90%。对回收前后样品的傅里叶变换红外光谱(FT-IR)和拉伸力学性能进行了测量。此外,在实验室固定床反应器中使用流化催化裂化(FCC)催化剂进行催化热解,同样以模型聚合物和废品作为原材料。对所得气体和油的分析表明,热解产生的主要是由一系列烃类(烷烃和烯烃)组成的脂肪族成分,具有作为生产新塑料或精炼燃料的原料回用于石化行业的巨大潜力。