Horvath Robert, Ramsden Jeremy J
Nanotechnology Centre, Department of Materials, Cranfield University, Bedfordshire, United Kingdom.
Langmuir. 2007 Aug 28;23(18):9330-4. doi: 10.1021/la701405n. Epub 2007 Aug 7.
Thin films assembled on a substrate are often anisotropic. Nevertheless, because of experimental limitations, sufficient parameters to characterize the anisotropy, even in the simplest (and perhaps most common) case of uniaxial thin films, which are birefringent, are not usually available. This paper examines the consequences of treating them as isotropic thin films, with particular reference to their characterization via perturbation of the propagation constants (effective refractive indices) of optical waveguides. It is shown that the refractive index and geometrical thickness of a thin film thus calculated are often unrealistic (especially when the thin film is positively birefringent), but the mass per unit area may be quite precise, depending on the sign and magnitude of the birefringence.
组装在基底上的薄膜通常是各向异性的。然而,由于实验限制,即使在最简单(可能也是最常见)的单轴双折射薄膜情况下,通常也没有足够的参数来表征各向异性。本文研究了将它们视为各向同性薄膜的后果,特别是通过光波导传播常数(有效折射率)的微扰来对其进行表征。结果表明,这样计算出的薄膜折射率和几何厚度通常是不现实的(特别是当薄膜是正双折射时),但单位面积质量可能相当精确,这取决于双折射的符号和大小。