Agg Kent M, Barnett Neil W, Lewis Simon W, Pearson James R
School of Life and Environmental Sciences, Deakin University, Geelong, Vic.3217, Australia.
J Forensic Sci. 2007 Sep;52(5):1111-4. doi: 10.1111/j.1556-4029.2007.00424.x.
The use of tris(2,2'-bipyridyl) ruthenium (III) as a chemiluminescent spray reagent spot-test for heroin is discussed. Two forms of the reagent are investigated an aqueous and an anhydrous where both were found to give vastly different results. The aqueous reagent giving slow, low intensity chemiluminescence whilst the anhydrous reagent gave a fast, bright response in the presence of 3,6-diacetylmorphine. The anhydrous reagent is less sensitive the slow, intensity response is characteristic of only two opiates tested 3,6-diacetylmorphine and 3-monoacetylmorphine.
讨论了使用三（2,2'-联吡啶）钌（III）作为海洛因化学发光喷雾试剂斑点试验的情况。研究了该试剂的两种形式——水性和无水形式，发现两者产生的结果大不相同。水性试剂产生缓慢、低强度的化学发光，而无水试剂在3,6-二乙酰吗啡存在下给出快速、明亮的响应。无水试剂的灵敏度较低，缓慢、高强度的响应是所测试的仅两种阿片类药物3,6-二乙酰吗啡和3-单乙酰吗啡的特征。
