Science. 1995 Mar 31;267(5206):1935-9. doi: 10.1126/science.267.5206.1935.
Various static and dynamic phenomena displayed by glass-forming liquids, particularly those near the so-called "fragile" limit, emerge as manifestations of the multidimensional complex topography of the collective potential energy function. These include non-Arrhenius viscosity and relaxation times, bifurcation between the alpha- and beta-relaxation processes, and a breakdown of the Stokes-Einstein relation for self-diffusion. This multidimensional viewpoint also produces an extension of the venerable Lindemann melting criterion and provides a critical evaluation of the popular "ideal glass state" concept.
玻璃形成液体所表现出的各种静态和动态现象,特别是那些接近所谓的“脆弱”极限的现象,都是集体势能函数多维复杂地形的表现。这些现象包括非阿仑尼乌斯粘度和弛豫时间、α-和β-弛豫过程之间的分叉,以及自扩散的斯泰克-爱因斯坦关系的破裂。这种多维观点还扩展了古老的林德曼熔融标准,并对流行的“理想玻璃态”概念进行了批判性评估。