Hyde J F
Science. 1965 Feb 19;147(3660):829-36. doi: 10.1126/science.147.3660.829.
The silicones are in most cases relatively complex mixtures rather than pure molecular species. Their structures and chemical properties can be controlled, however, with sufficient reproducibility to give compositions with unique characteristics. The organic groups serve not only as a device for controlling the siloxane structures, but offer an important means of modifying the physical and chemical properties. Studies of the inductive effects in the organosilicon compounds enhance our understanding of the nature of chemical bonds. In each field of application an extensive technology has developed for the adaptation of silicones to special needs. The possibility of new compositions to serve science and technology seems to be unlimited.
在大多数情况下,硅氧烷是相对复杂的混合物,而非纯分子物种。然而,它们的结构和化学性质能够得到足够的重现性控制,从而得到具有独特特性的组合物。有机基团不仅作为控制硅氧烷结构的一种手段,还提供了改变物理和化学性质的重要方法。对有机硅化合物中诱导效应的研究增进了我们对化学键本质的理解。在每个应用领域,都已发展出广泛的技术,以使硅氧烷适应特殊需求。新组合物服务于科学和技术的可能性似乎是无限的。