Brune W H, Anderson J G, Toohey D W, Fahey D W, Kawa S R, Jones R L, McKenna D S, Poole L R
Science. 1991 May 31;252(5010):1260-6. doi: 10.1126/science.252.5010.1260.
The nature of the Arctic polar stratosphere is observed to be similar in many respects to that of the Antarctic polar stratosphere, where an ozone hole has been identified. Most of the available chlorine (HCl and ClONO(2)) was converted by reactions on polar stratospheric clouds to reactive ClO and Cl(2)O(2) throughout the Arctic polar vortex before midwinter. Reactive nitrogen was converted to HNO(3), and some, with spatial inhomogeneity, fell out of the stratosphere. These chemical changes ensured characteristic ozone losses of 10 to 15% at altitudes inside the polar vortex where polar stratospheric clouds had occurred. These local losses can translate into 5 to 8% losses in the vertical column abundance of ozone. As the amount of stratospheric chlorine inevitably increases by 50% over the next two decades, ozone losses recognizable as an ozone hole may well appear.
据观测,北极极地平流层的性质在许多方面与南极极地平流层相似,南极已出现臭氧空洞。在冬季中期之前,北极极涡中的大部分可用氯(HCl和ClONO₂)通过极地平流层云表面的反应转化为活性ClO和Cl₂O₂。活性氮转化为HNO₃,其中一些在空间上不均匀地脱离平流层。这些化学变化导致在出现极地平流层云的极涡内高度处,臭氧特征性损失达10%至15%。这些局部损失可转化为臭氧垂直柱总量5%至8%的损失。由于平流层氯含量在未来二十年中将不可避免地增加50%,很可能会出现可识别为臭氧空洞的臭氧损失。