Chen Banglin, Ma Shengqian, Hurtado Eric J, Lobkovsky Emil B, Zhou Hong-Cai
Department of Chemistry, University of Texas-Pan American, Edinburg, Texas 78541-2999, USA.
Inorg Chem. 2007 Oct 15;46(21):8490-2. doi: 10.1021/ic7014034. Epub 2007 Sep 14.
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).
合成并表征了一种具有三重贯穿原始立方网络的微孔金属有机骨架Zn(ADC)(4,4'-Bpe)(0.5)·xG [1；ADC = 4,4'-偶氮苯二甲酸酯，4,4'-Bpe = 反式双(4-吡啶基)乙烯，G = 客体分子]。活化后的1a具有约3.4×3.4 Å的孔，对H₂/N₂、H₂/CO和CO₂/CH₄表现出高度选择性吸附行为。
