Chen Banglin, Ma Shengqian, Hurtado Eric J, Lobkovsky Emil B, Liang Chengdu, Zhu Haoguo, Dai Sheng
Department of Chemistry, University of Texas-Pan American, Edinburg, Texas 78541-2999, USA.
Inorg Chem. 2007 Oct 15;46(21):8705-9. doi: 10.1021/ic7013573. Epub 2007 Sep 20.
A microporous metal-organic framework 1 Co(NDC)(4,4'-Bipy)(0.5).G(x) (NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bipy = 4,4'-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 degrees C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.
一种微孔金属有机骨架1 Co(NDC)(4,4'-联吡啶)(0.5).G(x)（NDC = 2,6-萘二甲酸；4,4'-联吡啶 = 4,4'-联吡啶；G = 客体分子）被合成并对其双重互穿的原始立方网络结构进行了表征。为利用该骨架的灵活性，1分别在150和200摄氏度下活化形成1a和1b，它们对氢气表现出比氮气分子更高的选择性吸附行为。
