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在微流控装置中通过磁泳法从催化杂质中连续纯化单壁碳纳米管。

Magnetophoretic continuous purification of single-walled carbon nanotubes from catalytic impurities in a microfluidic device.

作者信息

Kang Joo H, Park Je-Kyun

机构信息

Department of Bio and Brain Engineering, Korea Advanced Institute of Science and Technology, 335 Gwahangno, Yuseong-gu, Daejeon 305-701, Korea.

出版信息

Small. 2007 Oct;3(10):1784-91. doi: 10.1002/smll.200700334.

Abstract

A magnetophoretic continuous purification method is presented of single-walled carbon nanotubes (SWCNTs) from the superparamagnetic iron-catalyst impurities in a microfluidic device without any influence on inherent SWCNT properties. By employing microfluidics and a magnetic-field-induced saw-tooth nickel microstructure, a highly enhanced magnetic force in adjoining microchannels is exploited. The iron impurities of SWCNTs are attracted towards areas of higher magnetic-flux density in the microchannels where magnetic field was asymmetrically generated perpendicularly to the streamline. We obtained highly purified SWCNTs at a rate of 0.36 mg h(-1) and that are estimated to be about 99% purity.

摘要

本文提出了一种磁泳连续纯化方法,用于在微流控装置中从超顺磁性铁催化剂杂质中分离单壁碳纳米管(SWCNT),且不会对SWCNT的固有性质产生任何影响。通过采用微流控技术和磁场诱导的锯齿状镍微结构,利用相邻微通道中高度增强的磁力。SWCNT中的铁杂质被吸引到微通道中磁通密度较高的区域,在该区域磁场垂直于流线不对称产生。我们以0.36 mg h⁻¹的速率获得了高纯度的SWCNT,估计纯度约为99%。

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