• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones.

作者信息

Shintani Ryo, Murakami Masataka, Hayashi Tamio

机构信息

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

出版信息

J Am Chem Soc. 2007 Oct 17;129(41):12356-7. doi: 10.1021/ja073997f. Epub 2007 Sep 26.

DOI:10.1021/ja073997f
PMID:17894493
Abstract
摘要

相似文献

1
Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones.γ-亚甲基-δ-戊内酯作为环加成反应的偶联试剂：钯催化与硝酮的[4 + 3]环加成反应
J Am Chem Soc. 2007 Oct 17;129(41):12356-7. doi: 10.1021/ja073997f. Epub 2007 Sep 26.
2
Palladium-catalyzed asymmetric decarboxylative lactamization of gamma-methylidene-delta-valerolactones with isocyanates: conversion of racemic lactones to enantioenriched lactams.钯催化γ-亚甲基-δ-戊内酯与异氰酸酯的不对称脱羧内酰胺化反应：外消旋内酯向对映体富集内酰胺的转化
J Am Chem Soc. 2008 Dec 3;130(48):16174-5. doi: 10.1021/ja807662b.
3
Palladium-catalyzed intramolecular decarboxylative allylic arylation of alpha-aryl-gamma-methylidene-delta-valerolactones.钯催化的α-芳基-γ-亚甲基-δ-戊内酯的分子内脱羧烯丙基芳基化反应。
Chem Commun (Camb). 2010 Mar 14;46(10):1697-9. doi: 10.1039/b924416f. Epub 2010 Feb 4.
4
Mechanistic investigation of the palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isocyanates: kinetic studies and origin of the site selectivity in the nucleophilic attack at a (pi-allyl)palladium.钯催化γ-亚甲基-δ-戊内酯与异氰酸酯的脱羧环化反应的机理研究：动力学研究及（π-烯丙基）钯中亲核进攻的位点选择性的起源。
J Am Chem Soc. 2010 Jun 2;132(21):7508-13. doi: 10.1021/ja1023223.
5
Palladium-catalyzed synthesis of spiro[2.4]heptanes: ligand-dependent position control in the nucleophilic attack to a pi-allylpalladium intermediate.钯催化的螺[2.4]庚烷的合成：亲核进攻π-烯丙基钯中间体时的配体依赖性位置控制
J Am Chem Soc. 2007 Dec 5;129(48):14866-7. doi: 10.1021/ja077236o. Epub 2007 Nov 10.
6
Synthesis of nine-membered azlactones by palladium-catalyzed ring-expansion of γ-methylidene-δ-valerolactones with aziridines.钯催化γ-亚甲基-δ-戊内酯与氮丙啶的环扩张反应合成九元氮杂环丁酮。
J Org Chem. 2011 Jun 3;76(11):4776-80. doi: 10.1021/jo2006158. Epub 2011 May 10.
7
Palladium-Catalyzed Dearomative [4 + 2]-Cycloaddition toward Hydrocarbazoles.钯催化的朝向氢化咔唑的脱芳构化[4+2]环加成反应。
J Org Chem. 2023 Jan 6;88(1):97-105. doi: 10.1021/acs.joc.2c01869. Epub 2022 Dec 9.
8
Palladium-catalyzed [3 + 3] cycloaddition of trimethylenemethane with azomethine imines.钯催化三亚甲基甲烷与甲亚胺亚胺的[3 + 3]环加成反应。
J Am Chem Soc. 2006 May 17;128(19):6330-1. doi: 10.1021/ja061662c.
9
Synthesis of spirocyclic C-arylglycosides and -ribosides by ruthenium-catalyzed cycloaddition.钌催化环加成合成螺环C-芳基糖苷和C-芳基核糖苷
Chem Asian J. 2007 Nov 5;2(11):1388-99. doi: 10.1002/asia.200700077.
10
Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones.钯催化三亚甲基甲烷衍生物与硝酮的不对称[3+3]环加成反应
Angew Chem Int Ed Engl. 2007;46(31):5901-3. doi: 10.1002/anie.200701529.

引用本文的文献

1
Recent Advances in Palladium-Catalyzed [4 + n] Cycloaddition of Lactones, Benzoxazinanones, Allylic Carbonates, and Vinyloxetanes.钯催化内酯、苯并恶嗪酮、烯丙基碳酸酯和乙烯基环氧乙烷的[4 + n]环加成反应的最新进展。
Top Curr Chem (Cham). 2023 Nov 3;381(6):33. doi: 10.1007/s41061-023-00442-9.
2
Chemodivergence in Pd-catalyzed desymmetrization of allenes: enantioselective [4+3] cycloaddition, desymmetric allenylic substitution and enynylation.钯催化联烯去对称化反应中的化学发散：对映选择性[4+3]环加成、去对称化联烯基取代反应和烯炔化反应。
Chem Sci. 2023 Sep 21;14(39):10812-10823. doi: 10.1039/d3sc04581a. eCollection 2023 Oct 11.
3
Fungicide-inspired precursors of π-allylpalladium intermediates for palladium-catalyzed decarboxylative cycloadditions.
用于钯催化脱羧环加成反应的受杀菌剂启发的π-烯丙基钯中间体前体
Chem Sci. 2023 Feb 21;14(11):3024-3029. doi: 10.1039/d3sc00112a. eCollection 2023 Mar 15.
4
Combining palladium and ammonium halide catalysts for Morita-Baylis-Hillman carbonates of methyl vinyl ketone: from 1,4-carbodipoles to ion pairs.钯与卤化铵催化剂相结合用于甲基乙烯基酮的Morita-Baylis-Hillman碳酸酯：从1,4-碳偶极子到离子对
Chem Sci. 2021 Jul 22;12(34):11399-11405. doi: 10.1039/d1sc03517g. eCollection 2021 Sep 1.
5
Stereoselective access to [5.5.0] and [4.4.1] bicyclic compounds through Pd-catalysed divergent higher-order cycloadditions.通过钯催化的发散高阶环加成反应获得[5.5.0]和[4.4.1]双环化合物的立体选择性途径。
Nat Chem. 2020 Sep;12(9):860-868. doi: 10.1038/s41557-020-0503-7. Epub 2020 Jul 27.
6
-Diastereoselective Syntheses of γ-Lactones by Visible Light-Iodine-Mediated Carboesterification of Alkenes.-可见光-碘介导的烯烃碳酯化反应实现γ-内酯的非对映选择性合成
ACS Omega. 2019 Mar 5;4(3):4856-4870. doi: 10.1021/acsomega.9b00333. eCollection 2019 Mar 31.
7
Phosphine-Catalyzed [3+2] and [4+3]Annulation Reactions of C,N-Cyclic Azomethine Imines with Allenoates.磷化氢催化的C,N-环甲亚胺亚胺与烯丙酸酯的[3+2]和[4+3]环化反应
Adv Synth Catal. 2012 Apr 26;354(6):1023-1034. doi: 10.1002/adsc.201100831.
8
Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.高选择性催化剂依赖的β-亚甲基-β-硅氧基-β-酰胺-α-重氮乙酰酸盐的 1,2-C→C、-O→C 和-N→C 迁移的竞争反应。
J Am Chem Soc. 2013 Jan 30;135(4):1244-7. doi: 10.1021/ja311392m. Epub 2013 Jan 17.
9
Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.对映选择性脱羧烷基化反应：催化剂开发、底物范围和机理研究。
Chemistry. 2011 Dec 9;17(50):14199-223. doi: 10.1002/chem.201003383. Epub 2011 Nov 14.
10
Phosphine-catalyzed annulations of azomethine imines: allene-dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] pathways.膦催化的亚胺氮杂环丙烷化反应：烯丙基依赖的[3 + 2]、[3 + 3]、[4 + 3]和[3 + 2 + 3]反应途径。
J Am Chem Soc. 2011 Aug 31;133(34):13337-48. doi: 10.1021/ja200231v. Epub 2011 Aug 3.