Gilmour Ryan, Prior Timothy J, Burton Jonathan W, Holmes Andrew B
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
Chem Commun (Camb). 2007 Oct 14(38):3954-6. doi: 10.1039/b709322e. Epub 2007 Aug 20.
A stereocontrolled synthesis of the core of eunicellin is described featuring a Claisen rearrangement and a diastereoselective organocatalytic Diels-Alder reaction as the key steps.
描述了一种对映选择性合成海兔毒素核心结构的方法，该方法以克莱森重排反应和非对映选择性有机催化的狄尔斯-阿尔德反应为关键步骤。
