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作为用于染发受损头发的洗发水,分散在两性表面活性剂溶液中的阳离子组合物的结构与性能

Structure and performance of cationic assembly dispersed in amphoteric surfactants solution as a shampoo for hair damaged by coloring.

作者信息

Nagahara Yasuo, Nishida Yuichi, Isoda Masanori, Yamagata Yoshifumi, Nishikawa Naoki, Takada Koji

机构信息

Beauty Care Research Laboratories, Lion Corporation, Edogawa-ku, Tokyo, Japan.

出版信息

J Oleo Sci. 2007;56(6):289-95. doi: 10.5650/jos.56.289.

Abstract

In recent years, hair coloring gains popularity as a trend of consumer's hair care. This coloring frequently damages hair. In response to this, a new shampoo-base was developed for repairing hair damaged by coloring. The new shampoo-base was prepared by dispersing cationic assembly in a solution of amphoteric surfactants. The mixture of behenyl trimethyl ammonium chloride (C22TAC) and behenyl alcohol (C22OH) was applied as the cationic assembly, which are dispersed in amido propyl betaine laurate (LPB) solution. LPB, which behaves as an amphoteric surfactant, was used as the wash-base. It was verified from the results on the measurements of DSC, calorimeter polarization, cryo-SEM and X-ray diffraction that the cationic assembly has a crystalline structure in the LPB solution. The new shampoo-base was highly efficient to change the color-damaged hair from hydrophilic to hydrophobic. The friction level of the hair washed with the new shampoo-base recovered to the same state as that of healthy hair. The exfoliation of cuticle was reduced after washing with the new shampoo-base.

摘要

近年来,染发作为一种消费者护发潮流而广受欢迎。这种染发方式常常会损伤头发。针对这一情况,人们研发了一种新型洗发剂基液,用于修复因染发而受损的头发。这种新型洗发剂基液是通过将阳离子聚集体分散在两性表面活性剂溶液中制备而成的。将二十二烷基三甲基氯化铵(C22TAC)和二十二醇(C22OH)的混合物用作阳离子聚集体,将其分散在月桂酰胺丙基甜菜碱(LPB)溶液中。LPB作为一种两性表面活性剂,用作洗涤基液。通过差示扫描量热法(DSC)、量热计极化、低温扫描电子显微镜(cryo-SEM)和X射线衍射测量结果证实,阳离子聚集体在LPB溶液中具有晶体结构。这种新型洗发剂基液能高效地将受损发质从亲水性转变为疏水性。用这种新型洗发剂基液洗发后,头发的摩擦系数恢复到与与健康发质。用这种新型洗发剂基液洗发后,角质层的剥落减少。

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