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热膨胀失配和疲劳载荷对烤瓷Y-TZP氧化锆盘相变的影响。

Influence of thermal expansion mismatch and fatigue loading on phase changes in porcelain veneered Y-TZP zirconia discs.

作者信息

de Kler M, de Jager N, Meegdes M, van der Zel J M

机构信息

Department of Dental Materials Science, Academisch Centrum Tandheelkunde Amsterdam, Universiteit van Amsterdam and Vrije Universiteit, Amsterdam, The Netherlands.

出版信息

J Oral Rehabil. 2007 Nov;34(11):841-7. doi: 10.1111/j.1365-2842.2006.01675.x.

Abstract

There is a rapidly growing interest for the use of Y-TZP zirconia as core material in veneered all-ceramic prostheses. It was hypothesized that a mismatch in coefficient of thermal expansion between the veneering porcelain and the Y-TZP zirconia core of these prostheses causes transformation of the tetragonal to the monoclinic structure in Y-TZP zirconia at the interface boundary when exposed to fatigue loading, resulting in fracture at the interface boundary. Y-TZP zirconia discs were veneered with three porcelains differing in coefficient of thermal expansion. Finite element analysis was used to investigate the stress distribution in the bi-layered discs because of the mismatch in thermal expansion. Two of these three groups were fatigued with the veneering ceramic in tension. X-ray diffraction was used to measure the intensity of monoclinic and tetragonal zirconia phase present at the zirconia core surface after sintering, airborne abrasion, veneering, and fatigue loading. It was found that the sintered tetragonal structure was converted to monoclinic up to a depth of 27 mum after airborne abrasion, and reversed back to tetragonal after porcelain veneering with porcelain. Fatigue loading of veneered discs did not, even with the highest possible thermal mismatch stress, cause any conversion from tetragonal to monoclinic phase.

摘要

将钇稳定四方多晶氧化锆(Y-TZP)氧化锆用作贴面全瓷修复体的核材料,对此的兴趣正迅速增长。有人提出假说,这些修复体的贴面瓷与Y-TZP氧化锆核之间的热膨胀系数不匹配,会导致在承受疲劳载荷时,Y-TZP氧化锆在界面边界处由四方结构转变为单斜结构,从而在界面边界处发生断裂。用三种热膨胀系数不同的瓷对Y-TZP氧化锆圆盘进行贴面。由于热膨胀不匹配,采用有限元分析来研究双层圆盘中的应力分布。这三组中的两组对贴面陶瓷进行拉伸疲劳试验。利用X射线衍射测量烧结、空气喷砂、贴面和疲劳加载后氧化锆核表面单斜和四方氧化锆相的强度。结果发现,空气喷砂后,烧结的四方结构在深度达27μm处转变为单斜结构,用瓷进行贴面后又变回四方结构。即使存在可能的最高热失配应力,对贴面圆盘进行疲劳加载也不会导致从四方相到单斜相的任何转变。

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