氟代醇介质中二芳基碘鎓（III）盐的通用直接脱水方法。
Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media.
作者信息
Dohi Toshifumi, Ito Motoki, Morimoto Koji, Minamitsuji Yutaka, Takenaga Naoko, Kita Yasuyuki
机构信息
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.
出版信息
Chem Commun (Camb). 2007 Oct 28(40):4152-4. doi: 10.1039/b708802g. Epub 2007 Aug 3.
DOI:10.1039/b708802g
PMID:17925959
Abstract
We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.
摘要
我们发现，使用氟代醇介质极大地提高了芳烃与高价碘（III）化合物直接脱水缩合的效率和范围；这种清洁的方法在芳香族底物中具有广泛的适用性以及独特的选择性，并且即使在聚合物功能化中也非常高效。
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